The Maxwell equations are a set of four partial differential equations that describe the spatial and temporal behavior of electric and magnetic fields. The sources of time-independent electric and magnetic fields are the time-independent electric charge density and the steady current density respectively. The study of electric and magnetic phenomena that do not vary in time are called electrostatic and magnetostatic respectively.
When the spatial distribution of charges and currents are time-dependent new phenomena take place. In a time-varying situation, the electric and magnetic fields depend on time and their temporal derivatives become sources of the electromagnetic field besides and .
The electric and magnetic fields are vector quantities. A mathematical theorem due to Helmholtz asserts that to completely determine a vector field , it is enough to specify its divergence , and its curl (or rotational) , whenever these quantities decrease to zero sufficiently rapid at infinity. Maxwell equations precisely specify the divergence and rotational of the electric and magnetic fields in terms of their sources.
General form of Maxwell equations
Let’s recall here the Maxwell equations:
The charge density can be written as the sum of two contributions, namely , where is the density of free charges, while is the density of bound charges. The bound charge density is related to the polarization of the medium through the equation
Let’s see how Eq.(5) is obtained
Relation between bound charge density and polarization
The relation given in Eq.(5) is not an apriori definition. It is derived by considering the electrostatic potential due to a spatial distribution of pure dipoles. We recall here the electrostatic potential due to a single electric dipole , namely
The polarization is the density of dipoles defined as the vector sum of pure dipoles contained in an infinitesimal volume divided by that infinitesimal volume. Therefore, the expression represents the net dipole resulting of the vector sum of all of the dipoles contained in the infinitesimal element of volume . The electrostatic potential due to the polarization is therefore
Now we use the identity
inside the integral which becomes
In the preceding equations, means derivation with respect to the primed coordinates. The Leibnitz’ rule allows us to rewrite the integrand in Eq.(9) in the form
This implies that the electrostatic potential can be written as the sum of two terms, namely
The contribution to coming from Eq.(12) looks like the potential due to a charge distribution whose density is precisely given by Eq.(5).
The volume integral in Eq.(11) can be transformed to a surface integral with the help of the divergence theorem, namely
where the integral extends over the surface of the body. The contribution to coming from Eq.(13) looks like the potential due to a surface charge distribution whose density is
where denotes the surface of the volume occupied by the body and is the unit vector normal to the surface.
The surface charge density cannot be used with the differential form of the Gauss’ law Eq.(1) which is valid inside the body only. Nevertheless, the no inclusion of the surface charge density induced by the polarization, in the definition of the bound charge density , does not represent a problem. Indeed, the integral form of Gauss’ law is valid everywhere and the surface charge density does not contribute either (this is so because a volume integral has the same value independently of whether the boundary is included or not).
Gauss’ law inside matter
The first of Maxwell equations, Eq.(1) is the differential form of Gauss law. In terms of the free and bound charge densities it can be rewritten as follows:
The partial differential equation is identical to the Gauss law given in Eq.(1). It just has been written in a form that makes explicit the fact that the medium responds to the electric field by becoming polarized. How exactly the polarization depends on the electric field is a problem that has to be analyzed separately.
Ampere’s law inside matter
Ampere’s law with the modification made by Maxwell to include the effect on the magnetic field due to a time varying electric field , is given in Eq.(4). The current density has three contributions coming from free charges , bound charges , and polarization effects . The bound current density is related to the magnetization of the medium through the equation
We will not derive here the relation given in Eq.(16), but we remark that it is obtained in a similar way to the derivation of Eq.(5) in the case of magnetostatic. The polarization current density has its origin in the continuous displacement of bound charges in response to a time varying electric field. The continuous displacement of bound charges creates a time varying polarization. The equation relating to the time varying polarization is
The decomposition , together with Eq.(16) and Eq.(17), allows rewriting Ampere’s law Eq.(4) as follows:
Equations (2), (3), (15) and (18), are known as Maxwell equations in matter. Actually, they just make explicit that the material responds to electric and magnetic fields through polarization and magnetization. Note that Eq.(2) and Eq.(3), including no explicit relation with charges and currents, remain unaltered.